https://ogma.newcastle.edu.au/vital/access/ /manager/Index en-au 5 Hydrogeochemical and ecological risk assessments of trace elements in the coastal surface water of the southern Caspian Sea https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:39746  Fe (73.6) > Zn (67.8) > Mn (29.9) > Cu (5.7) > Mo (3.7) > Cd (2.8) > Se (2.3) > V (1.9) > Co = As (1.8) > Sb (1.2) > Pb (0.6). TEs displayed high variations within samples, reflecting many sources that control their concentrations in the coastal water. Most TEs displayed elevated concentrations in the east and west of the study area. The Na-Cl water type in the majority of investigated sites indicates excess alkaline elements and strong acid anions relative to alkaline earth cations and weak acid anions. Considering the saturation states of minerals, carbonate and evaporite minerals are oversaturated and unsaturated in surface water, respectively. Compositional interrelations between aqueous species showed that reverse cation exchange may have occurred. The excess SO42− content, derived from irrigation return flow and domestic greywater, probably plays a crucial role in the mobilization and transport of Zn and Pb by binding to sulfate ligands and forming aqueous complexes. Ecological risk assessment of TEs revealed that water in the majority of sites is safe in terms of As, Se, Pb, and Cd content, and unsuitable with respect to Zn and Cu. Acute and chronic toxicities of Cu and Zn are reported in several sites, thus coastal water cannot be used for fishery and protecting “nature reserve” purposes. However, industrial activity and tourism are safe to be conducted in most coastal water sites.]]> Wed 07 Feb 2024 15:26:27 AEDT ]]> PET-microplastics as a vector for heavy metals in a simulated plant rhizosphere zone https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:40441 S-Zn > S-Pb and C-Zn > T-Cd > C-Pb. PET particles exposed to Zn, Cd, and Pb solution adsorbed from 7.2 to 8.5%, 5.3 to 9.8%, and 29.8 to 68.5% of the initial heavy metals concentration, respectively. 11.3 to 15.2%, 12.5 to 23.35%, and 5.5 to 33.6% of the initially adsorbed Zn, Cd, and Pb were desorbed in the wheat rhizosphere zone in the three defined scenarios, respectively. The results show that PET particles can act as a vector in transferring heavy metals to the rhizosphere zone.]]> Fri 22 Jul 2022 14:31:16 AEST ]]>